Chloroplatinic acid catalyzed cyclization of silanes bearing pendant acetylenic groups

DOI: 10.1016/0022-328X(89)85001-6

Source and publish data:

Journal of Organometallic Chemistry p. 1 - 16 (1989)

Update date:2022-08-04

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Authors:

Steinmetz, Mark G.

Udayakumar, B. S.

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Article abstract of DOI:10.1016/0022-328X(89)85001-6

Chloroplatinic acid catalyzed, intramolecular hydrosilylation of acetylenes of structure HMe2SinSiMe2CCR (R = H or Ph, n = 2 or 3) proceeds via syn addition of the Si-H group to the carbon triple bond to give, predominantly, cyclic products having an

Full text of DOI:10.1016/0022-328X(89)85001-6

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