Electrochemical synthesis of the vinylogs of N-acyl N,O-acetals and their reactivity

DOI: 10.1016/S0040-4039(00)88861-9

Source and publish data:

Tetrahedron Letters p. 1713 - 1716 (1990)

Update date:2022-07-30

Topics:

Authors:

Fasseur Fasseur

Rigo Rigo

Cauliez Cauliez

Debacker

Couturier

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Article abstract of DOI:10.1016/S0040-4039(00)88861-9

Vinylogs of N-acyl N,O-acetals are formed in good yields by anodic oxidation, in methanol or water, of β-enaminoesters derived from pyroglutamic acid. These new acetals react easily with nucleophiles or silylated amines.

Full text of DOI:10.1016/S0040-4039(00)88861-9

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Product name:Acetic acid, cyano[1-methyl-5-(phenylamino)-2-pyrrolidinylidene]-, methyl ester

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