Journal of the Chemical Society. Chemical communications p. 344 - 346 (1990)
Update date:2022-08-05
Topics:
Brewer, C.
The reaction of tetramesitylporphinatoiron(III) hydroxide with ethyl 3-mercaptopropionate in toluene generates the air and temperature stable five co-ordinate iron(III) monothiolate complex, which adds imidazole or other Lewis base to give a six co-ordinate adduct, the unusual stability of which allows characterisation by UV-VIS spectrophotometry at room temperature.
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