Helvetica Chimica Acta p. 169 - 173 (1990)
Update date:2022-08-05
Topics:
Toder, Bruce H.
Mullen, George B.
Georgiev, Vassil St.
Adamantanone-derived nitrone 4 and some other keto-nitrones, when reacted with aromatic and aliphatic aldehydes in refluxing toluene or tetrahydrofuran, formed the corresponding aldonitrones (Z)-10, the latter arising from the fragmentation of an initially formed 1,4,2-dioxazolidine 6 to adamantan-2-one and an oxaziridine intermediate 11, which then rearranges to (Z)-10.
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