Synthesis of Allylazo Compounds by Reactions of Aryldiazonium Salts with Allylsilanes

DOI: 10.1021/jo00030a001

Source and publish data:

Journal of Organic Chemistry p. 1057 - 1059 (1992)

Update date:2022-08-05

Topics:

Authors:

Mayr, Herbert

Grimm, Klaus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00030a001

Aryldiazonium tetrafluoroborates react with allylsilanes to yield allylazo compounds.If the allylic carbon attached to the azo group carries hydrogen, tautomerization with formation of hydrazones takes place.

Full text of DOI:10.1021/jo00030a001

Products guided by the article

Product name:Diazene, (2,4-dinitrophenyl)(2-ethylidene-1-methylcyclopentyl)-

Cas No:138061-21-9

R&D Labs maybe for 138061-21-9

Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
Guangzhou PI & PI Biotech Inc. Ltd.

Contact:+86-20-81716320

Address:13th Floor, Xinbao Technology Industrial Park, No. 2 Ruixiang Road, Huangpu District, Guangzhou,Guangdong,China
Shanghai He Yang International Trading Co., Ltd.

Contact:+86-21-52043598

Address:Room 816, Blag.5, No.58 Huachi Road
QINGDAO HONG JIN CHEMICAL CO.,LTD.

website:http://www.hongjinchem.com

Contact:+86-532-83657313

Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.
Chengdu Cogon Bio-tech Co., Ltd.

Contact:86-28-85171192

Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.

Relevant to this article

Molecular design of new hydrazone dyes for dye-sensitized solar cells: Synthesis, characterization and DFT study

Doi:10.1016/j.molstruc.2012.02.035
(2012)
Total synthesis and dual PPARα/γ agonist effects of Amorphastilbol and its synthetic derivatives

Doi:10.1016/j.bmcl.2012.04.062
(2012)
Total synthesis and anticancer activity studies of the stereoisomers of asperphenamate and patriscabratine

Doi:10.1016/j.cclet.2009.10.004
(2010)
Combinatorial solid-phase synthesis of 4,6-diaryl and 4-aryl, 6-alkyl-1,3,5-triazines and their application to efficient biofuel production

Doi:10.1021/co300007a
(2012)
Electronic nature of substituent X governs reaction mechanism in aminolysis of 4-pyridyl X-substituted-benzoates in acetonitrile

Doi:10.1021/jo300961y
(2012)
Chemoenzymatic synthesis of GDP-L-fucose derivatives as potent and selective α-1,3-fucosyltransferase inhibitors

Doi:10.1002/adsc.201100940
(2012)

Article Doi