Synthesis of Allylazo Compounds by Reactions of Aryldiazonium Salts with Allylsilanes

DOI: 10.1021/jo00030a001

Source and publish data:

Journal of Organic Chemistry p. 1057 - 1059 (1992)

Update date:2022-08-05

Topics:

Authors:

Mayr, Herbert

Grimm, Klaus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00030a001

Aryldiazonium tetrafluoroborates react with allylsilanes to yield allylazo compounds.If the allylic carbon attached to the azo group carries hydrogen, tautomerization with formation of hydrazones takes place.

Full text of DOI:10.1021/jo00030a001

Products guided by the article

Product name:Diazene, (2,4-dinitrophenyl)(2-ethylidene-1-methylcyclopentyl)-

Cas No:138061-21-9

R&D Labs maybe for 138061-21-9

Synchem Pharma Co.,Ltd(expird)

Contact:+0086-21-61984905-1

Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Nanjing Samwon International Limited

Contact:+86-25-84873444

Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,

Relevant to this article

Molecular design of new hydrazone dyes for dye-sensitized solar cells: Synthesis, characterization and DFT study

Doi:10.1016/j.molstruc.2012.02.035
(2012)
Total synthesis and dual PPARα/γ agonist effects of Amorphastilbol and its synthetic derivatives

Doi:10.1016/j.bmcl.2012.04.062
(2012)
Total synthesis and anticancer activity studies of the stereoisomers of asperphenamate and patriscabratine

Doi:10.1016/j.cclet.2009.10.004
(2010)
Combinatorial solid-phase synthesis of 4,6-diaryl and 4-aryl, 6-alkyl-1,3,5-triazines and their application to efficient biofuel production

Doi:10.1021/co300007a
(2012)
Electronic nature of substituent X governs reaction mechanism in aminolysis of 4-pyridyl X-substituted-benzoates in acetonitrile

Doi:10.1021/jo300961y
(2012)
Chemoenzymatic synthesis of GDP-L-fucose derivatives as potent and selective α-1,3-fucosyltransferase inhibitors

Doi:10.1002/adsc.201100940
(2012)

Article Doi