Synthesis of Allylazo Compounds by Reactions of Aryldiazonium Salts with Allylsilanes

DOI: 10.1021/jo00030a001

Source and publish data:

Journal of Organic Chemistry p. 1057 - 1059 (1992)

Update date:2022-08-05

Topics:

Authors:

Mayr, Herbert

Grimm, Klaus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00030a001

Aryldiazonium tetrafluoroborates react with allylsilanes to yield allylazo compounds.If the allylic carbon attached to the azo group carries hydrogen, tautomerization with formation of hydrazones takes place.

Full text of DOI:10.1021/jo00030a001

Products guided by the article

Product name:Diazene, (2,4-dinitrophenyl)(2-ethylidene-1-methylcyclopentyl)-

Cas No:138061-21-9

R&D Labs maybe for 138061-21-9

zhengzhou Triz Pharma-Tech Co., Ltd

website:http://www.Trizpharma-tech.com

Contact:+86-0371-86597269，53392065

Address:High-tech Industrial Development Zone, Zhengzhou City, NO.7 Holly Street
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI

Relevant to this article

Molecular design of new hydrazone dyes for dye-sensitized solar cells: Synthesis, characterization and DFT study

Doi:10.1016/j.molstruc.2012.02.035
(2012)
Total synthesis and dual PPARα/γ agonist effects of Amorphastilbol and its synthetic derivatives

Doi:10.1016/j.bmcl.2012.04.062
(2012)
Total synthesis and anticancer activity studies of the stereoisomers of asperphenamate and patriscabratine

Doi:10.1016/j.cclet.2009.10.004
(2010)
Combinatorial solid-phase synthesis of 4,6-diaryl and 4-aryl, 6-alkyl-1,3,5-triazines and their application to efficient biofuel production

Doi:10.1021/co300007a
(2012)
Electronic nature of substituent X governs reaction mechanism in aminolysis of 4-pyridyl X-substituted-benzoates in acetonitrile

Doi:10.1021/jo300961y
(2012)
Chemoenzymatic synthesis of GDP-L-fucose derivatives as potent and selective α-1,3-fucosyltransferase inhibitors

Doi:10.1002/adsc.201100940
(2012)

Article Doi