ADDITION OF CARBON RADICALS TO 4',5'-UNSATURATED URACILNUCLEOSIDES BY THE USE OF ORGANOSELENIUM REAGENTS: A NEW STEREOSELECTIVE ENTRY TO C-C BOND FORMATION AT THE 5'-POSITION

Article abstract of DOI:10.1016/S0040-4039(00)94378-8

Addition of carbon radicals generated from organoselenium reagents (PhSeR: R= COPh, CO2Et, CH2CO2Et, CH2COMe, and CH2CN) to 4',5'-unsaturated uracilnucleosides was found to provide a highly efficient entry to C-C bond formation at the 5'-position, the ste