Tetrahedron Letters p. 6705 - 6708 (1989)
Update date:2022-08-04
Topics:
Ando, Wataru
Kako, Masahiro
Akasaka, Takeshi
Nagase, Shigeru
Kawai, Takatoshi
et al.
Singlet oxygenation of 1,1,2,2-tetramesityl-1,2-disilirane 1a afforded the corresponding cyclic peroxide 3a.Trapping experiments and theoretical studies of the initially formed peroxidic intermediate were also carried out.Peroxonium ion type intermediate is required to rationalize the results.
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