Tetrahedron p. 3657 - 3664 (1999)
Update date:2022-09-26
Topics:
Dayan, Sharon
Bareket, Yifat
Rozen, Shlomo
The complex HOF·CH3CN, made directly from fluorine and aqueous acetonitrile, was used for α-hydroxylation of various ketones, esters and acids via their trimethyl silyl enol ethers. The reaction is usually complete in a few minutes at room temperature or below and has high yields.
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