HEXAMETHYLDISILANE AS A SOURCE OF BOTH TRIMETHYLSILYL AND PENTAMETHYLDISILYL ANIONS. FORMATION OF A SUBSTITUTED PENTAMETHYLDISILYL STABLE ENOL

DOI: 10.1016/0040-4039(90)87033-V

Source and publish data:

Tetrahedron Letters p. 555 - 558 (1990)

Update date:2022-09-26

Topics:

Authors:

Nadler, Ella B.

Rappoport, Zivi

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Article abstract of DOI:10.1016/0040-4039(90)87033-V

The reaction of dimesitylketene with MeLi/Me3SiSiMe3 gives in addition to the expected 2,2-dimesityl-1-trimethylsilylethenol, also the unexpected stable simple enol 2,2-dimesityl-1-pentamethyldisilylethenol.

Full text of DOI:10.1016/0040-4039(90)87033-V

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