HEXAMETHYLDISILANE AS A SOURCE OF BOTH TRIMETHYLSILYL AND PENTAMETHYLDISILYL ANIONS. FORMATION OF A SUBSTITUTED PENTAMETHYLDISILYL STABLE ENOL

DOI: 10.1016/0040-4039(90)87033-V

Source and publish data:

Tetrahedron Letters p. 555 - 558 (1990)

Update date:2022-09-26

Topics:

Authors:

Nadler, Ella B.

Rappoport, Zivi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(90)87033-V

The reaction of dimesitylketene with MeLi/Me3SiSiMe3 gives in addition to the expected 2,2-dimesityl-1-trimethylsilylethenol, also the unexpected stable simple enol 2,2-dimesityl-1-pentamethyldisilylethenol.

Full text of DOI:10.1016/0040-4039(90)87033-V

Products guided by the article

Product name:Ethenol, 1-(pentamethyldisilanyl)-2,2-bis(2,4,6-trimethylphenyl)-

Cas No:128333-74-4

R&D Labs maybe for 128333-74-4

Qingdao Pana-Life Biochem Co.,Ltd.

Contact:86-532-87683902

Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021
Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning

Relevant to this article

A removable auxiliary for amidomercuration reactions: The stereoselective preparation of substituted N-acyl pyrrolidines and piperidines

Doi:10.1016/S0040-4039(00)70687-3
(1989)
Unique chemoselective Strecker-type reaction of acetals with TMSCN catalyzed by MgI₂ etherate

Doi:10.1080/00397911.2019.1711413
(2020)
BORYLATION OF α-HYDROXYALKYLPHOSPHINE OXIDES IN THE PRESENCE OF STRONG BASES

Doi:10.1007/BF00960348
()
On the structure of PHB (=Poly[(R)-3-hydroxybutanoic acid]) in phospholipid bilayers: Preparation of trifluoromethyl-labeled oligo[(R)-3-hydroxybutanoic acid] derivatives

Doi:10.1002/hlca.200490222
(2004)
Partially OH Depleted Calix<4>arenes

Doi:10.1021/jo00002a010
(1991)
Thiamine coenzyme models: Imidazolinium ylides and the reactions of 2-(hydroxyalkyl)imidazolines

Doi:10.1016/S0040-4039(00)88877-2
(1990)

Article Doi