2-Fluoromethyl-4,4,6-trimetiiyl-1,3-oxasine as a new reagent for the preparation of α-fluoroaldehydes

DOI: 10.1016/S0040-4039(00)94364-8

Source and publish data:

Tetrahedron Letters p. 179 - 182 (1990)

Update date:2022-08-02

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Authors:

Patrick, Timothy B.

Hosseini, Sedigheh

Bains, Satinder

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Article abstract of DOI:10.1016/S0040-4039(00)94364-8

The title compound easily forms an anion on treatment with n-butyllithium. The anion reacts with electrophiles such as alkyl halides, aldehydes, and ketones. The resulting products furnish α-fluoroaldehydes after reduction and hydrolysis.

Full text of DOI:10.1016/S0040-4039(00)94364-8

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