Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 101 - 107 (1990)
Update date:2022-08-02
Topics:
Smolyakova, I. P.
Smit, V. A.
Lutsenko, A. I.
Daeva, E. D.
Reaction of methoxyallene with arylsulphenyl chlorides proceeds nonselectively with formation of mixtures of 1,2- and 2,3-arylthiochloro adducts, the composition of which depends on the nature of the reagent and solvent. ?-Donating compounds of various types in the presence of Lewis acids are alkylated by adducts of methoxyallene with arylsulphenyl chlorides and primarily products are formed by attack at the C3 atom of the reagent.
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