Journal of Organic Chemistry p. 4622 - 4634 (1990)
Update date:2022-08-03
Topics: Selectivity binding affinity Supramolecular Chemistry Functional Groups Non-covalent Interactions Host-Guest Complexation Preorganized Macrocyclic effect
Bryant, Judi A.
Helgeson, Roger C.
Knobler, Carolyn B.
deGrandpre, Mark P.
Cram, Donald J.
The synthesis and free energies are reported for 10 new hemispherands (1, 2, 4, 6, 7-9, 11-13) binding alkali metal and ammonium picrate salts at 25 deg C in CDCl3 saturated with D2O.These hemispherands possess the general structure I, in which two 4-subs
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