Journal of Organic Chemistry p. 4981 - 4983 (1990)
Update date:2022-08-04
Topics:
Welch, John T.
Corte, Bart De
Kimpe, Norbert De
The 3-aza-Cope rearrangement of α-halogenated and nonhalogenated ketimines by deprotonation of the corresponding iminium salts was found to be an especially facile and regioselective process.Deuterium labeling studies supported the proposed mechanism which required the rearrangement to be highly concerted.
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