A NOVEL 1,3 O -> C SILYL REARRANGEMENT IN CARBOHYDRATE CHEMISTRY: SYNTHESIS OF α-D-GLYCOPYRANOSYLTRIMETHYLSILANES

DOI: 10.1016/S0040-4020(01)97585-4

Source and publish data:

Tetrahedron p. 77 - 88 (1990)

Update date:2022-07-29

Topics:

Authors:

Pedretti, Valerie

Veyrieres, Alain

Sinay, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)97585-4

Reductive lithiation of 2-O-trimethylsilyl derivatives of phenyl thiogluco and -galactopyranosides gives rise to a 1,3 O -> C silyl migration leading to α-D-gluco and -galactopyranosyltrimethylsilanes in good yields.The expected β-elimination is observed

Full text of DOI:10.1016/S0040-4020(01)97585-4

Products guided by the article

Product name:(2S,3R,4S,5S,6R)-2-Phenylsulfanyl-3,4,5-tris-trimethylsilanyloxy-6-trimethylsilanyloxymethyl-tetrahydro-pyran

Cas No:128848-57-7

R&D Labs maybe for 128848-57-7

Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd

Contact:0086-10-64430626

Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China

Relevant to this article

Suppression of the skin response to alantolactone in alantolactone-sensitized guinea pigs treated with N-acetyl-L-cysteinyl-L-alanine methyl ester

Doi:10.1016/0223-5234(90)90017-W
(1990)
Synthesis and Analgesic Activity of 4,7-Dimethyl-3,4,4a,5,8,8a-Hexahydro-2-Chromen-4,8-Diols Containing Alkyl-Substituted Aromatic Moieties

Doi:10.1007/s10600-017-2202-1
(2017)
Synthesis, biopharmaceutical characterization, antimicrobial and antioxidant activities of 1-(4′-O-β-d-glucopyranosyloxy-2′- hydroxyphenyl)-3-aryl-propane-1,3-diones

Doi:10.1016/j.ejmech.2011.01.068
(2011)
Copper-catalyzed oxidative trifluoromethylation of benzylic sp³ C-H bond adjacent to nitrogen in amines

Doi:10.1016/j.tetlet.2011.02.038
(2011)
Elucidation of a structural basis for the inhibitor-driven, p62 (SQSTM1)-dependent intracellular redistribution of cAMP phosphodiesterase-4A4 (PDE4A4)

Doi:10.1021/jm200070e
(2011)
Regioselective rapid analog synthesis of 1,3-(or 1,5-)diphenyl-4-aryl/ heteroaryl-5-(or 3-)(methylthio)pyrazoles via Suzuki cross-coupling

Doi:10.1016/j.tet.2011.02.043
(2011)

Article Doi