Competition between charge transfer via superexchange and thermally activated energy transfer in porphyrinheterodimer-quinone systems

DOI: 10.1016/0009-2614(95)00982-A

Source and publish data:

Chemical Physics Letters p. 253 - 261 (1995)

Update date:2022-08-05

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Authors:

Rempel, U.

Maltzan, B. von

Borczyskowski, C. von

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Article abstract of DOI:10.1016/0009-2614(95)00982-A

Electron transfer is observed in semi-rigid heterodimers of free base and zinc porphyrin covalently linked to the electron acceptor p-benzoquinone (Q).The rate of transfer critically depends on the relative spatial arrangement of the zinc and free-base po

Full text of DOI:10.1016/0009-2614(95)00982-A

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