Diastereoselective 1,4-addition of various nucleophiles to 5-trimethylsilyl-2-cyclohexenone: Synthesis of (+)-ramulosin

DOI: 10.1016/S0040-4020(01)81963-3

Source and publish data:

Tetrahedron p. 1541 - 1552 (1990)

Update date:2022-08-05

Topics:

Authors:

Asaoka, Morio

Sonoda, Shuzo

Fujii, Naoaki

Takei, Hisashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)81963-3

Base catalyzed reaction of active methylene compounds or oxygen catalyzed reaction of trialkylboranes via radical pathway with 5-trimethylsilyl-2-cyclohexenone (1) gave the corresponding products with modest to high (3:2- 20:1) diastereopurities. High dia

Full text of DOI:10.1016/S0040-4020(01)81963-3

Products guided by the article

Product name:3-(methoxycarbonylmethyl)-5-(trimethylsilyl)cyclohexanone

Cas No:129156-52-1

R&D Labs maybe for 129156-52-1

Hangzhou utanpharma Co., Ltd

Contact:86-571-87758773

Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Synasia Inc

Contact:17316303296

Address:240 Amboy Ave
Rugao Jinling Chemical Co., Ltd.(expird)

Contact:0086-513-68005586

Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang
Shanghai Pinewood Fine Chemical Co., Ltd.

website:http://www.pinewoodchem.com

Contact:0086-21-62417129，62414096

Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai

Relevant to this article

Synthesis, reactions and antitumour screening of new enaminones

Doi:10.3184/030823410X12878479991509
(2010)
Synthesis of medium-sized ring ethers from thionolactones, applications to polyether synthesis

Doi:10.1021/ja00173a013
(1990)
A facile route for the synthesis of 1-[5-hydroxy-3-methyl-1-(2-thiazolyl)-4-pyrazolyl)-1,3-butanediones from dehydroacetic acid

Doi:10.1080/00397919308011286
(1993)
Synthesis of novel dihydroxydiphosphines and dihydroxydicarboxylic acids having a tetra(thio-1,3-phenylene-2-yl) backbone

Doi:10.1080/10610278.2010.514913
(2011)
New access to 5-substituted 1,3-benzothiazol-2(3 H)-ones and their N -methyl analogues by a palladium coupling reaction

Doi:10.1055/s-0030-1258377
(2011)
An effective method to prepare imines from aldehyde, bromide/epoxide, and aqueous ammonia

Doi:10.1021/jo102455q
(2011)

Article Doi