Diastereoselective 1,4-addition of various nucleophiles to 5-trimethylsilyl-2-cyclohexenone: Synthesis of (+)-ramulosin

DOI: 10.1016/S0040-4020(01)81963-3

Source and publish data:

Tetrahedron p. 1541 - 1552 (1990)

Update date:2022-08-05

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Authors:

Asaoka, Morio

Sonoda, Shuzo

Fujii, Naoaki

Takei, Hisashi

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Article abstract of DOI:10.1016/S0040-4020(01)81963-3

Base catalyzed reaction of active methylene compounds or oxygen catalyzed reaction of trialkylboranes via radical pathway with 5-trimethylsilyl-2-cyclohexenone (1) gave the corresponding products with modest to high (3:2- 20:1) diastereopurities. High dia

Full text of DOI:10.1016/S0040-4020(01)81963-3

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Product name:3-(methoxycarbonylmethyl)-5-(trimethylsilyl)cyclohexanone

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