Allylsilanes in organic synthesis; convenient preparation of synthetic intermediates by catalytic hydrosilation of acetylenic alcohols

Article abstract of DOI:10.1016/S0040-4039(00)94428-9

Synthetically useful vinylsilane-alcohols such as (1) can be easily prepared by the catalytic hydrosilation of the appropriate acetylenic alcohols in high yield, and with excellent regio- and stereoselectivity, without the need to protect the hydroxyl gro