A Complex Induced Proximity Effect in the Anionic Fries Rearrangement of o-Iodophenyl Benzoates: Synthesis of Dihydro-O-methylsterigmatocystin and Other Xanthones

DOI: 10.1021/jo00302a011

Source and publish data:

Journal of Organic Chemistry p. 4520 - 4522 (1990)

Update date:2022-08-02

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Authors:

Horne, Stephen

Rodrigo, Russell

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Article abstract of DOI:10.1021/jo00302a011

The success of an anionic Fries rearrangement, used to synthesise dihydro-O-methylsterigmatocystin and other xanthones, is dependent on the presence of a remote methoxyl substituent.

Full text of DOI:10.1021/jo00302a011

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