Journal of the Chemical Society. Perkin transactions I p. 901 - 905 (1990)
Update date:2022-08-02
Topics:
Hasegawa, Tadashi
Ogawa, Takuya
Miyata, Kazuko
Karakizawa, Atsushi
Komiyama, Mikiko
et al.
The (ω-dialkylamino)alkyl β-oxoesters (1) undergo photocyclization via remote hydrogen transfer to give the medium-sized azalactones (2) and/or aminolactones (3).Intramolecular electron transfer from nitrogen to the excited carbonyl group of (1) occurs prior to the remote hydrogen transfer.
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