Synthesis of stable silicon heterocycles by reaction of organic substrates with a chlorosilylene [PhC(NtBu)2SiCl]

DOI: 10.1002/chem.201001901

Source and publish data:

Chemistry - A European Journal p. 4283 - 4290 (2011)

Update date:2022-08-02

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Authors:

Khan, Shabana

Sen, Sakya S.

Kratzert, Daniel

Tavcar, Gasper

Roesky, Herbert W.

Stalke, Dietmar

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Article abstract of DOI:10.1002/chem.201001901

Heteroleptic chlorosilylene (PhC(NtBu)₂SiCl) (1) reacts with unsaturated organic compounds under oxidative addition. Reactions of 1 with cyclooctatetraene (COT) and a diimine afford [1+4]-cycloaddition products 3 and 6, respectively. In the cas

Full text of DOI:10.1002/chem.201001901

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