Triple bonds between molybdenum and tungsten atoms supported by selenolate ligands: M2(SeAr)6 and M2(OPri) 2(SeAr)4 (Ar = mesityl)

DOI: 10.1039/C39900000920

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 920 - 921 (1990)

Update date:2022-07-29

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Authors:

Chisholm, Malcolm H.

Parkin, Ivan P.

Huffman, John C.

Streib, William B.

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Article abstract of DOI:10.1039/C39900000920

The reactions between M₂(NMe₂)₆ and mesityl (Ar) selenol (>6 equiv.) in toluene yield M₂(SeAr) ₆ compounds as red-brown crystals while related reactions involving M₂(OR)₆ yield M

Full text of DOI:10.1039/C39900000920

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Product name:(W((C(CH₃)CHC(CH₃)CHC(CH₃)C)Se)2(OCH(CH₃)2))2

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