Selective fluorination of o- and m-carboranes. Synthesis of 9-monofluoro-, 9,12-difluoro-1, 8,9,12-trifluoro-, and 8,9,10,12-tetrafluoro-o-carboranes and 9-monofluoro-, and 9,10-difluoro-m-carboranes. Molecular structure of 8,9,10,12-tetrafluoro-o-carbora

DOI: 10.1016/0022-328X(90)85001-F

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Journal of Organometallic Chemistry p. 307 - 318 (1990)

Update date:2022-08-06

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Authors:

Lebedev, V.N.

Balagurova, E.V.

Polyakov, A.V.

Yanovsky, A.I.

Struchkov, Yu.T.

Zakharkin, L.I.

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Article abstract of DOI:10.1016/0022-328X(90)85001-F

Reaction of o- and m-carboranes with antimony pentafluoride results in replacement of hydrogen by fluorine at the boron atoms, to give in succession 9-fluoro-; 9,12-difluoro-; 8,9,12-trifluoro-; 8,9,10,12-tetrafluoro-o-carboranes and 9-fluoro-; 9,10-diflu

Full text of DOI:10.1016/0022-328X(90)85001-F

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