A Convenient 2-Deoxy-α-D-glucopyranosylation Reaction Using Dimethylphosphinothioate Method

Article abstract of DOI:10.1246/cl.1990.849

Several 2-deoxy-α-glucosides were obtained in good yields with high stereoselectivity by glycosylation reaction of the corresponding alcohols with 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl dimethylphosphinothioate in the presence of a catalytic amount of triphenylmethylium perchlorate or an equivalent amount of silver perchlorate.