1,4-Addition of Optically Active Transferable Ligands from Organocuprates. Generation and Reaction of Homochiral α-Alkoxyorganocuprates

DOI: 10.1021/jo00307a004

Source and publish data:

Journal of Organic Chemistry p. 5428 - 5430 (1990)

Update date:2022-07-30

Topics:

Authors:

Linderman, Russell J.

Griedel, Brian D.

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Article abstract of DOI:10.1021/jo00307a004

Homochiral higher order cyano α-alkoxyorganocuprate addition to ynoates and enones occurs with 0-97percent retention of configuration; results that imply multiple reaction pathways may be operative in 1,4-addition of these species.

Full text of DOI:10.1021/jo00307a004

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