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Facile Retro Diels-Alder Reaction of a Pentamethyltricyclo2,6>decenone Derivative: Synthesis of (+)-15(S)-Prostaglandin A2

DOI: 10.1039/c39900000410

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 410 - 412 (1990)

Update date:2022-09-26

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Authors:

Grieco, Paul A.Grieco, Paul A.

Abood, NormanAbood, Norman

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Article abstract of DOI:10.1039/c39900000410

The incorporation of methyl groups into the C(1), C(7), C(8), C(9), and C(10) positions of tricyclo<5.2.1.02,6>decenone (1) dramatically accelerates the retro Diels-Alder reaction of (3) under Lewis acid catalysis thus permitting access to synt

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Product name:(Z)-7-{(1R,2S)-2-[(E)-(S)-3-(tert-Butyl-diphenyl-silanyloxy)-oct-1-enyl]-5-oxo-cyclopent-3-enyl}-hept-5-enoic acid

Cas No:129944-69-0

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