Tetrahedron Letters p. 4463 - 4466 (1990)
Update date:2022-08-03
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The first benzazadiphosphole 4 with an intracyclic phosphorus phosphorus double bond was obtained starting from the anilino 2 phosphine. The stability of 4 is due to the aromaticity of the fused cycles. 4 has been isolated and characterized by its physico-chemical data; it reacts according to a [4+2] cycloaddition with the dimethylbutadiene.
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Doi:10.1016/0022-328X(90)80172-V
(1990)Doi:10.1021/jo980844p
(1998)Doi:10.1039/CT9252700735
(1925)Doi:10.1080/07328309608005670
(1996)Doi:10.1016/S0040-4020(01)89963-4
(1987)Doi:10.1002/adsc.201100554
(2012)