Tetrahedron Letters p. 4463 - 4466 (1990)
Update date:2022-08-03
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The first benzazadiphosphole 4 with an intracyclic phosphorus phosphorus double bond was obtained starting from the anilino 2 phosphine. The stability of 4 is due to the aromaticity of the fused cycles. 4 has been isolated and characterized by its physico-chemical data; it reacts according to a [4+2] cycloaddition with the dimethylbutadiene.
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(1998)Doi:10.1039/CT9252700735
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(2012)
