Preparation of cyclohexenyl derivatives by the ring-opening reactions of oxabicyclo[2.2.1] compounds with cuprates

DOI: 10.1016/S0040-4039(00)89036-X

Source and publish data:

Tetrahedron Letters p. 3253 - 3256 (1990)

Update date:2022-08-05

Topics:

Authors:

Lautens, Mark

Catherine Smith

Abd-El-Aziz, Alaa S.

Huboux, Alexandre H.

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Article abstract of DOI:10.1016/S0040-4039(00)89036-X

The ring-opening reaction of 7-oxabicyclo[2.2.1]hept-5-enes with cuprates is described. S_N2′ attack with retention of configuration is the predominant pathway.

Full text of DOI:10.1016/S0040-4039(00)89036-X

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