Synthesis and Circular Dichroism of Optically Pure (+/-)-(1S,2S,5S)-5-Methoxy-3,4,6,7-tetramethylidenebicyclooct-2-yl Derivatives. Baker's Yeast Reduction of 4-Methoxy-5,6,7,8-tetramethylidenebicyclooctan-2-one

DOI: 10.1002/hlca.19900730425

Source and publish data:

Helvetica Chimica Acta p. 985 - 1001 (1990)

Update date:2022-08-02

Topics:

Authors:

Burnier, Gerald

Vogel, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19900730425

Baker's yeast reduction of 4-methoxy-5,6,7,8-tetramethylidenebicyclo<2.2.2>octan-2-one (11) under fermenting conditions afforded (-)-(1S,2S,4R)-4-methoxy-5,6,7,8-tetramethylidenebicyclo<2.2.2>octan-2-ol ((-)-13) in 60percent yield with an e.e. > 99.5perce

Full text of DOI:10.1002/hlca.19900730425

Products guided by the article

Product name:(+)-(1S,2S,4R)-4-Methoxy-5,6,7,8-tetramethylidenebicyclo<2.2.2>oct-2-yl 4-(Dimethylamino)benzoate

Cas No:130423-23-3

R&D Labs maybe for 130423-23-3

Chengdu Baishixing Science and Technology Industry Co., Ltd.

website:http://www.cd-bsx.com

Contact:+86-28-88531548

Address:#217,North of Industry Road,Heshan Town,Pujiang County,Chengdu,Sichuan,China.
Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
Jiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd

Contact:+86-517-86283327

Address:9 North Hantai Road, Huaian, China
AUSHUN PHARMACEUTICAL TECHNOLOGY CO,.LTD

Contact:+86-25-86883560 15951806178

Address:14 Dayingbi, Zhujiang Rd. East, Nanjing, Jiangsu, China.
Ceresking Ecology & Technology co.,ltd

Contact:86 22 66218397

Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.

Relevant to this article

SYNTHESIS OF 2- AND 4-NITROPYRIMIDINES AND 2-NITRO-sym-TRIAZINES BY OZONIZATION OF HYDROXYAMINO AND NITROSO DERIVATIVES

Doi:10.1007/BF00487433
(1990)
Stereoselective construction of three- and four-contiguous asymmetric centers: Novel possibility by alkylative rearrangement of epoxy silyl ethers

Doi:10.1016/S0040-4039(00)89058-9
(1990)
A convergent process to C-2 substituted penems via addition of thiols and organocuprates to an O-triflylthioketene acetal

Doi:10.1016/S0040-4039(00)89046-2
(1990)
Improved procedure for the regiospecific synthesis of 2'-deoxyribonucleosides

Doi:10.1016/S0040-4039(00)97641-X
(1990)
Synthesis and application of a recyclable ionic liquid-supported imidazolidinone catalyst in enantioselective 1,3-dipolar cycloaddition

Doi:10.1039/c2cc31830j
(2012)
Cross-coupling reactions of pyrimidin-2-yl sulfonates with phenols and anilines: An efficient approach to C2-functionalized pyrimidines

Doi:10.1002/cjoc.201300536
(2013)

Article Doi