A Novel Synthesis of Primary Selenoamides from Nitriles by the Treatment of Bis(trimethylsilyl) Selenide and BF3*OEt2

DOI: 10.1246/cl.1990.1403

Source and publish data:

Chemistry Letters p. 1403 - 1406 (1990)

Update date:2022-07-29

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Authors:

Shimada, Kazuaki

Hikage, Shigeki

Takeishi, Yoshiyuki

Takikawa, Yuji

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Article abstract of DOI:10.1246/cl.1990.1403

Reaction of nitriles with (Me3Si)2Se in the presence of BF3*OEt2 afforded the corresponding primary selenoamides in moderate yields.A selenourea and a selenothiocarbamate were also prepared in a similar manner from the corresponding cyanamide and thiocyanate.

Full text of DOI:10.1246/cl.1990.1403

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