Journal of Organic Chemistry p. 2801 - 2804 (1991)
Update date:2022-08-04
Topics:
Hu, Chang-Ming
Qing, Feng-Ling
Huang, Wei-Yuan
The reaction of perfluoroalkanesulfinates, RfCF2SO2Na, with allyl and propargyl halides, in the presence of (NH4)2S2O8, gave 3-(perfluoroalkyl)prop-1-enes (RfCH2CH=CH2) and 3-(perfluoroalkyl)allenes (RfCH=C=CH2), respectively, in good yield.Evidence is presented for a radical addition-elimination mechanism for the reaction.The reaction represents a synthetically viable and convenient route to such compounds.
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