Reaction of Perfluoroalkanesulfinates with Allyl and Propargyl Halides. A Convenient Synthesis of 3-(Perfluoroalkyl)prop-1-enes and 3-(Perfluoroalkyl)allenes

DOI: 10.1021/jo00008a041

Source and publish data:

Journal of Organic Chemistry p. 2801 - 2804 (1991)

Update date:2022-08-04

Topics:

Authors:

Hu, Chang-Ming

Qing, Feng-Ling

Huang, Wei-Yuan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00008a041

The reaction of perfluoroalkanesulfinates, R_fCF2SO2Na, with allyl and propargyl halides, in the presence of (NH4)2S2O8, gave 3-(perfluoroalkyl)prop-1-enes (R_fCH2CH=CH2) and 3-(perfluoroalkyl)allenes (R_fCH=C=CH2), respectively, in good yield.Evidence is presented for a radical addition-elimination mechanism for the reaction.The reaction represents a synthetically viable and convenient route to such compounds.

Full text of DOI:10.1021/jo00008a041

Products guided by the article

Product name:4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,2-undecadiene

Cas No:130716-22-2

R&D Labs maybe for 130716-22-2

Yicheng Goto Pharmaceuticals Co.,Ltd.

Contact:+86 710 3423122

Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China
TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town
Dongying J&M Chemical Co., Ltd,

Contact:546-8551108

Address:Room 1219, Zisheng Mansion, Zibo Road, Dongying, Shandong, China
Zhuhai Rundu Pharmaceutical co.,Ltd

Contact:+86-756-7630755

Address:No.6,North Airport Road,Sanzao Town,Jinwan District
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.

Contact:15857995878 0579-82207761

Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua

Relevant to this article

Doi:10.1021/ja01564a038
(1957)
Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes

Doi:10.1039/c0ob01119c
(2011)
Design, synthesis, and structure-activity relationship studies of thiophene-3-carboxamide derivatives as dual inhibitors of the c-Jun N-terminal kinase

Doi:10.1016/j.bmc.2011.03.017
(2011)
Organocatalytic ?±-addition of isocyanides to aldehydes

Doi:10.1002/ejoc.201403313
(2015)
Reaction of 2-methoxycarbonylamino-3,3-dichloroacrylonitrile with phenylhydrazine in the presence of triethylamine

Doi:10.1134/S1070363211030327
(2011)
Organocatalytic stereoselective direct aldol reaction of trifluoroethyl thioesters

Doi:10.1002/adsc.201100122
(2011)

Article Doi