Tetrahedron Letters p. 4965 - 4968 (1990)
Update date:2022-08-03
Topics:
Blizzard, Timothy A.
Mrozik, Helmut
Preiser, Franz A.
Fisher, Michael H.
Avermectin B1-3,4-oxide (2) has been synthesized from avermectin B1 (1). While epoxide 2 is comparable to avermectin B1 in bioactivity, opening of the epoxide leads to derivatives which are substantially less bioactive.
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