Rhodium-catalyzed asymmetric addition of potassium organotrifluoroborates to N-sulfonyl ketimines

DOI: 10.1021/ol200958q

Source and publish data:

Organic Letters p. 2977 - 2979 (2011)

Update date:2022-08-03

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Authors:

Shintani, Ryo

Takeda, Momotaro

Soh, Ying-Teck

Ito, Tomoaki

Hayashi, Tamio

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Article abstract of DOI:10.1021/ol200958q

A rhodium-catalyzed asymmetric addition of readily available potassium organotrifluoroborates to both N-tosyl and N-nosyl ketimines has been developed. High enantioselectivity has been achieved by using a chiral diene ligand, and the nosyl group of the ad

Full text of DOI:10.1021/ol200958q

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