Autoxidation Reaction Mechanism for L-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis

DOI: 10.1271/bbb.62.811

Source and publish data:

Bioscience, Biotechnology and Biochemistry p. 811 - 813 (1998)

Update date:2022-08-02

Topics:

Authors:

Miyake, Noriko

Kurata, Tadao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1271/bbb.62.811

The autoxidation mechanism for L-ascorbic acid (ASA)-related compounds such as D-arabo-ascorbic acid (= erythorbic acid; ERA) and triose reductone (TR) in methanol without metal ion catalysis was studied.The oxidation reaction of these ASA-related compounds seems to proceed via the C(2) oxygen adduct of ERA (or TR) by a similar reaction mechanism to that of ASA. - Keywords: L-ascorbic acid; autoxidation; D-erythorbic acid; triose reductone; C(2) oxygen adduct

Full text of DOI:10.1271/bbb.62.811

Products guided by the article

Product name:2(3H)-Furanone, dihydro-3,4-dihydroxy-

Cas No:13092-55-2

R&D Labs maybe for 13092-55-2

Evershine Chemical CO Ltd

Contact:+86-571-87010026

Address:202, Zhenhua Road,
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Changzhou Sunsheng Chem Co., Ltd

Contact:+1-(989)-854-0648

Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601

Relevant to this article

Stereo- and Regiocontrol of Electrophilic Additions to Cyclohexene Systems by Neighboring Groups. Competition of Electronic and Stereoelectronic Effects and Comparison of the Reactivity of Selected Electrophiles

Doi:10.1021/jo00308a014
(1990)
Highly regio- and diastereoselective anionic [3 + 2] cycloaddition under phase transfer catalytic conditions

Doi:10.1021/jo2005268
(2011)
New applications of solid silica chloride (SiO₂-Cl) in organic synthesis. Efficient preparation of diacetals of 2,2-bis(hydroxymethyl)-1,3-propanediol from different substrates and their transthioacetalization reactions. Efficient regeneration of carbonyl compounds from acetals and acylals

Doi:10.1080/10426500214879
(2002)
Efficient synthesis of amino-protected calix[4]arenes selectively functionalized with iron chelator ICL670 designed as platform for iron recognition

Doi:10.1016/j.tet.2011.02.059
(2011)
Enantioselective conjugate addition of malononitrile to chalcones promoted by α,α-L-diaryl prolinols: Noncovalent versus covalent catalysis?

Doi:10.1002/ejoc.201001466
(2011)
Synthesis of NMR (¹H and ¹³C). Studies of azole of Diclofouime

Doi:10.1002/jhet.5570270326
(1990)

Article Doi