Autoxidation Reaction Mechanism for L-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis

DOI: 10.1271/bbb.62.811

Source and publish data:

Bioscience, Biotechnology and Biochemistry p. 811 - 813 (1998)

Update date:2022-08-02

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Authors:

Miyake, Noriko

Kurata, Tadao

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Article abstract of DOI:10.1271/bbb.62.811

The autoxidation mechanism for L-ascorbic acid (ASA)-related compounds such as D-arabo-ascorbic acid (= erythorbic acid; ERA) and triose reductone (TR) in methanol without metal ion catalysis was studied.The oxidation reaction of these ASA-related compounds seems to proceed via the C(2) oxygen adduct of ERA (or TR) by a similar reaction mechanism to that of ASA. - Keywords: L-ascorbic acid; autoxidation; D-erythorbic acid; triose reductone; C(2) oxygen adduct

Full text of DOI:10.1271/bbb.62.811

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