Stereo- and Regiocontrol of Electrophilic Additions to Cyclohexene Systems by Neighboring Groups. Competition of Electronic and Stereoelectronic Effects and Comparison of the Reactivity of Selected Electrophiles

DOI: 10.1021/jo00308a014

Source and publish data:

Journal of Organic Chemistry p. 5580 - 5589 (1990)

Update date:2022-08-02

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Authors:

Kocovsky, Pavel

Pour, Milan

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Article abstract of DOI:10.1021/jo00308a014

Neighboring group participation in the addition of Br+, I+, PhSeX, Hg2+, Tl3+, and Pd2+ to a series of steroidal olefins 5-13 has been studied.The relative importance of the electronic (Markovnikov) and stereoelectronic effects has been assessed.In cases

Full text of DOI:10.1021/jo00308a014

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