Synthesis of Nitrogen-Containing Polycycles via Rhodium(II)-Induced Cyclization-Cycloaddition and Insertion Reactions of N-(Diazoacetoacetyl)amides. Conformational Control of Reaction Selectivity

DOI: 10.1021/jo00002a058

Source and publish data:

Journal of Organic Chemistry p. 820 - 829 (1991)

Update date:2022-08-04

Topics:

Authors:

Doyle, Michael P.

Pieters, Roland J.

Taunton, Jack

Pho, Hoan Q.

Padwa, Albert

et al. et al.

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Article abstract of DOI:10.1021/jo00002a058

A series of diazoacetoacetamides, when treated with a catalytic quantity of a rhodium(II) carboxylate, were found to afford products derived from both a carbonyl ylide intermediate and intramolecular C-H insertion.With 3-(N-(diazoacetoacetyl)amino)propano

Full text of DOI:10.1021/jo00002a058

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