Highly stereoselective double Michael cyclization of 1-phenylsulfinyl and sulfonyl analogues of the nazarov reagent

DOI: 10.1016/S0040-4039(00)94474-5

Source and publish data:

Tetrahedron Letters p. 3969 - 3972 (1990)

Update date:2022-08-05

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Authors:

Spino, Claude

Deslongchamps, Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)94474-5

The base-catalyzed double Michael addition of the β-keto sulfoxide 5 with 2-carbomethoxy-2-cyclohexenone (1) proceeds, after elimination of the sulfoxide moiety during chromatography on silica, to give the dehydrodecalin adduct 6 with high stereoselectivi

Full text of DOI:10.1016/S0040-4039(00)94474-5

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