Electroorganic Chemistry. 130. A Novel Trifluoromethylation of Aldehydes and Ketones Promoted by an Electrogenerated Base

DOI: 10.1021/jo00001a002

Source and publish data:

Journal of Organic Chemistry p. 2 - 4 (1991)

Update date:2022-08-05

Topics:

Authors:

Shono, Tatsuya

Ishifune, Manabu

Okada, Toshio

Kashimura, Shigenori

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Article abstract of DOI:10.1021/jo00001a002

A base generated by the electroreduction of 2-pyrrolidone deprotonated trifluoromethane to form a trifluoromethyl anion equivalent.In the presence of hexamethyldisilazane, this species reacted with a variety of aldehydes and ketones to afford (trifluoromethyl)-carbinols in high yield.

Full text of DOI:10.1021/jo00001a002

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