Journal of Organic Chemistry p. 2 - 4 (1991)
Update date:2022-08-05
Topics:
Shono, Tatsuya
Ishifune, Manabu
Okada, Toshio
Kashimura, Shigenori
A base generated by the electroreduction of 2-pyrrolidone deprotonated trifluoromethane to form a trifluoromethyl anion equivalent.In the presence of hexamethyldisilazane, this species reacted with a variety of aldehydes and ketones to afford (trifluoromethyl)-carbinols in high yield.
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