Tetrahedron Letters p. 5349 - 5352 (1990)
Update date:2022-08-03
Topics:
Sakuraba, Hidetake
Ushiki, Shigeru
The anion of (S)-(-)-methyl 1-naphthyl sulfoxide reacts enantioselectively with alkyl phenyl ketones to give (SsSc)-β-hydroxysulfoxides with diastereomeric excess (de) up to 100percent.Optical pure (S)-tertiary alcohols are prepared by desulfurization of the corresponding diastereomers.
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