HIGHLY ENANTIOSELECTIVE ADDITION OF (S)-LITHIOMETHYL 1-NAPHTHYL SULFOXIDE TO KETONES

DOI: 10.1016/S0040-4039(00)98069-9

Source and publish data:

Tetrahedron Letters p. 5349 - 5352 (1990)

Update date:2022-08-03

Topics:

Authors:

Sakuraba, Hidetake

Ushiki, Shigeru

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Article abstract of DOI:10.1016/S0040-4039(00)98069-9

The anion of (S)-(-)-methyl 1-naphthyl sulfoxide reacts enantioselectively with alkyl phenyl ketones to give (SsSc)-β-hydroxysulfoxides with diastereomeric excess (de) up to 100percent.Optical pure (S)-tertiary alcohols are prepared by desulfurization of the corresponding diastereomers.

Full text of DOI:10.1016/S0040-4039(00)98069-9

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