Enantioselective Synthesis of The Hexahydrobenzofuran Subunit of The Avermectins and The Milbemycins

DOI: 10.1016/S0040-4039(00)94443-5

Source and publish data:

Tetrahedron Letters p. 3563 - 3566 (1990)

Update date:2022-08-03

Topics:

Authors:

Lee, Kwang-Chung

Wu, Jackson C. C.

Yen, Kuang-Fu

Uang, Biing-Jiun

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Article abstract of DOI:10.1016/S0040-4039(00)94443-5

A highly stereocontrolled route to the hexahydrobenzofuran subunit of the avermectins and milbemycins via an asymmetric Diels-Alder reaction is described.

Full text of DOI:10.1016/S0040-4039(00)94443-5

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Product name:Benzoic acid (1S,5S,6S)-5-bromo-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-oxo-cyclohex-2-enylmethyl ester

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