Journal of the Chemical Society. Perkin transactions II p. 1929 - 1934 (1990)
Update date:2022-08-04
Topics:
Cardelli, Liberato
Greci, Lucedio
Stipa, Pierluigi
Rizzoli, Corrado
Sgarabotto, Paolo
Ugozzoli, Franco
On treatment with Fenton's reagent in dimethyl sulphoxide nitrosoarenes form sulphonylate products, while the expected N,O-dimethylated hydroxylamine is isolated only in the case of nitrosobenzene in low yield.Nitrosobenzene and 4-cyanonitrosobenzene lead to N-sulphonylhydroxylamines while 4-nitroso-N,N-dimethylaniline and 1-nitroso-2-phenyl-3-acetylindolizine give sulphonamides and ring-sulphonylated products.A nitrenium cation is suggested to play a primary role in this process.X-Ray analysis of the title compound confirms that the trigonal planar arrangement of the dimethylamino group and its coplanarity with the benzene ring, as expected in accord with the results found in related derivatives.
View MoreSuzhou Lixin Pharmaceutical Co., Ltd.
Contact:86-512-88169812
Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Nanyang Tianhua pharmaceutical Co.,Ltd.
Contact:+8618639816203
Address:Longsheng Industrial Park
website:http://www.uvchemkeys.com
Contact:0086-021-58785816
Address:RM2607 Building No.1 Guosheng, Lane 388, Zhongjiang Road, Putuo District, Shanghai 200062 China
Shijiazhuang Frontierchem Co., Ltd.
Contact:+86-311-89271196
Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Fuxin Jintelai Fluorin Chemical Co., Ltd.
Contact:+86-0418-8229599
Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
Doi:10.1016/j.tet.2011.04.080
(2011)Doi:10.1002/chem.201304271
(2014)Doi:10.1016/j.tetlet.2014.02.034
(2014)Doi:10.1016/j.bmcl.2014.04.059
(2014)Doi:10.1016/S0040-4039(00)79959-X
(1994)Doi:10.1021/acs.orglett.0c02109
(2020)
