Angewandte Chemie - International Edition p. 5687 - 5690 (2011)
Update date:2022-08-03
Topics:
Bausch, Cory C.
Patman, Ryan L.
Breit, Bernhard
Krische, Michael J.
Stoichiometric metals banned: Nonsymmetrically disubstituted alkynes were converted into primary trisubstituted allylic alcohols upon exposure to paraformaldehyde in the presence of nickel or ruthenium catalysts, which exhibit complementary regioselectivity and complete stereoselectivity in the absence of exogenous reducing agents (see scheme). Copyright
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