β-Amino alcohols from amino acids: Chelation control via Schiff bases

DOI: 10.1016/S0040-4039(00)97784-0

Source and publish data:

Tetrahedron Letters p. 4985 - 4986 (1990)

Update date:2022-07-29

Topics:

Authors:

Polt Polt

Peterson

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Article abstract of DOI:10.1016/S0040-4039(00)97784-0

Sequential addition of iBu₂AlH and RLi or RMgX to Schiff base esters derived from amino acids provides a simple route to β-amino alcohols. The reaction procedes without racemization, and with high threo selectivity. Several representative sphingosines are synthesized.

Full text of DOI:10.1016/S0040-4039(00)97784-0

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