Chemistry Letters p. 1607 - 1610 (1990)
Update date:2022-08-05
Topics:
Kuroboshi, Manabu
Hiyama, Tamejiro
Arenecarbaldehydes ArCHO were allowed to react with a carbenoid reagent CF3CX2Mtl (X=Cl, Mtl=ZnCl, X=F, Mtl=LI) to give the adducts ArCH(OH)CX2CF3 whose hydroxyl group was substituted by fluorine.Dehydrohalogenating of the resultant ArCHFCX2CF3 (X=Cl or F
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