Steric factors in neutral and anionic alkyne complexes of tungsten(0)

DOI: 10.1021/om00048a028

Source and publish data:

Organometallics p. 494 - 500 (1991)

Update date:2022-08-02

Topics:

Authors:

Wink, Donald J.

Cooper, N. John

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Article abstract of DOI:10.1021/om00048a028

The labile W(0) source [W(CO)₃(NCC₂H₅)₃] (2) reacts with the bulky alkyne bis(trimethylsilyl)acetylene (BTMSA) under reduced pressure to give the tris(alkyne) complex [W(Me₃SiC≡CSiMe₃)

Full text of DOI:10.1021/om00048a028

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