Journal of the Chemical Society. Chemical communications p. 1315 - 1317 (1990)
Update date:2022-08-05
Topics:
Plater, M. John
Rees, Charles W.
Slawin, Alexandra M. Z.
Williams, David J.
Amino derivatives 3 of the trithiadiazepine ring are moderately stable crystalline solids, readily prepared from 6-bromotrithiadiazepine 1 and ammonia or amines under remarkably mild conditions; unusually for aromatic amines, the amino groups are tetrahedral and are not conjugated with, but are orthogonal to, the 10 ? heteroaromatic rings, all of which form infinite overlapping stacks in the crystals.
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