Tetrahedron Letters p. 5409 - 5412 (1990)
Update date:2022-07-29
Topics:
Swindell, Dharles S.
Blase, Frances Rose
Eggleston, Drake S.
Krause, Jeanette
Auxiliary-modified allylic sulfoxides 2-5 exhibit greatly biased ambient temperature sulfinyl epimeric equilibria brought about by the reversible sulfoxide-sulfenate rearrangement, and provide lithio anions that undergo highly regio- and diastereoselecrive conjugate addition reactions with cyclopentenone, and in the case of reagent 5, to cyclohexenone.
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