Synthesis of the aspidosperma skeleton through allylsilane N-acyliminium cyclization

DOI: 10.1016/S0040-4020(01)90540-X

Source and publish data:

Tetrahedron p. 4049 - 4062 (1990)

Update date:2022-08-05

Topics:

Authors:

Mittendorf, John

Hiemstra, Henk

Speckamp, W. Nico

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Article abstract of DOI:10.1016/S0040-4020(01)90540-X

A highly stereoselective synthesis of the Aspidosperma ring system is described, based on a combination of two stereocontrolled processes. The first features a base-catalyzed cyclization of the imine 5 to generate the indoline 4. The second involves the f

Full text of DOI:10.1016/S0040-4020(01)90540-X

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