A Stereoselective Route to Vicinally Substituted Cyclopentane- and Cyclobutane-carboxylates

DOI: 10.1039/c39880000760

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 760 - 761 (1988)

Update date:2022-08-05

Topics: Regioselectivity Diastereoselectivity Column chromatography Yield NMR spectroscopy Catalyst Nucleophile Electrophile Enantiomeric excess (ee) Deprotonation Mass spectrometry (MS) Cyclization Stereoselective Retrosynthetic analysis Substrate Chiral Auxiliary Reaction Optimization Ring Strain

Authors:

Kim, Deukjoon

Jang, Yoo Mi

Kim, In O

Park, Sang Woo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880000760

Intramolecular alkylation of the enolates derived from the esters (3) and (7) stereoselectively afforded the cyclopentanecarboxylate (4) and the cyclobutanecarboxylate (8), respectively; compound (8) is a potential intermediate for the synthesis of (+/-)-

Full text of DOI:10.1039/c39880000760

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(E)-5-benzoyloxy-2-methylpent-2-en-1-ol

Cas No:132352-25-1

R&D Labs maybe for 132352-25-1

Afine Chemicals Limited

website:http://www.afinechem.com

Contact:+86-571-85134551

Address:No. 206 Zhen Hua Road, Hangzhou 310030, Zhejiang, China
Tianjin Boron PharmaTech Co.,Ltd.(expird)

Contact:86-022-59845187

Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
JIANGXI ZHANGFENG CHEMICAL CO., LTD.

Contact:+86-0799-3413066

Address:Xiyuan village, Xiabu Town, Xiangdong District
Wuxi Olite Chemical Co., Ltd.

Contact:86-510-82853889

Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN

Relevant to this article

Transition-metal-free decarboxylative bromination of aromatic carboxylic acids

Doi:10.1039/c8sc01016a
(2018)
Asymmetric Darzens condensation on chiral η⁶Cr(CO)₃ complexed benzaldehydes

Doi:10.1016/S0040-4020(01)90079-1
(1990)
Rearrangement of 3,3-disubstituted 1-aryl-4,5-dihydro-5-oxo-3H-1,2,4-triazolium tetrafluoroborates; Part 3. An efficient synthesis of 1,5-heteroannulated 1,2-dihydro-2-phenyl-3H-1,2,4-triazol-3-ones

Doi:10.1055/s-1990-27090
(1990)
SYNTHESIS OF 1-<ω-(BENYHYDRYLPIPERAYIN-1-YL)ALKYLJINDOLES, 9-13-(4-BENZHYDRYLPIPERAZIN-1-YL)PROPYL)CARBAZOLE AND ITS DERIVATIVES AND THEIR ANTIALLERGIC ACTIVITY

Doi:10.1007/BF00766551
(1990)
The Synthesis of α-(<11C>Methyl)phenylalanine and α-(<¹¹C>Methyl)tyrosine from ¹¹C-Labelled Malonic Esters

Doi:10.1039/P19910000215
(1991)
The preparation of 2,4-dibromoestra-1,3,5(10),6-tetraene-3,17 β-diol diacetate

Doi:10.1016/0039-128X(91)90072-4
(1991)

Article Doi