A Stereoselective Route to Vicinally Substituted Cyclopentane- and Cyclobutane-carboxylates

DOI: 10.1039/c39880000760

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 760 - 761 (1988)

Update date:2022-08-05

Topics: Regioselectivity Diastereoselectivity Column chromatography Yield NMR spectroscopy Catalyst Nucleophile Electrophile Enantiomeric excess (ee) Deprotonation Mass spectrometry (MS) Cyclization Stereoselective Retrosynthetic analysis Substrate Chiral Auxiliary Reaction Optimization Ring Strain

Authors:

Kim, Deukjoon

Jang, Yoo Mi

Kim, In O

Park, Sang Woo

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Article abstract of DOI:10.1039/c39880000760

Intramolecular alkylation of the enolates derived from the esters (3) and (7) stereoselectively afforded the cyclopentanecarboxylate (4) and the cyclobutanecarboxylate (8), respectively; compound (8) is a potential intermediate for the synthesis of (+/-)-

Full text of DOI:10.1039/c39880000760

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