Asymmetric Synthesis via Heteroconjugate Addition: Valinol Template as Oxazolidine Heteroolefin vs Acetylenic Nucleophiles

DOI: 10.1016/S0040-4039(00)97882-1

Source and publish data:

Tetrahedron Letters p. 5499 - 5502 (1990)

Update date:2022-08-03

Topics:

Authors:

Isobe, Minoru

Hirose, Yumi

Shimokawa, Ken-ichiro

Nishikawa, Toshio

Goto, Toshio

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Article abstract of DOI:10.1016/S0040-4039(00)97882-1

The diastereoselective C-C bond forming reaction via heteroconjugate addition strategy was expanded for asymmetric synthesis.A valinol derivative was employed as chiral template to induce chelation control in the heteroconjugate addition of alkyls and alk

Full text of DOI:10.1016/S0040-4039(00)97882-1

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