1,3-Diol Fragmentation Using a Reactive Benzylic Hydroxyl Group as a Nucleofuge. Synthesis of a Tobacco Sesquiterpene

DOI: 10.1246/bcsj.64.50

Source and publish data:

Bulletin of the Chemical Society of Japan p. 50 - 56 (1991)

Update date:2022-07-29

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Authors:

Kato, Michiharu

Tooyama, Youichi

Yoshikoshi, Akira

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Article abstract of DOI:10.1246/bcsj.64.50

A benzylic hydroxyl group activated by electron-donative aromatic function was found to be a remarkably reactive nucleofuge for 1,3-diol fragmentation.Thus, treatment of α-(2,6-dimethoxy-4-methylphenyl)-2β-hydroxy-2α,5,5,8aβ-tetramethyl-4aα-decahydro-1β-n

Full text of DOI:10.1246/bcsj.64.50

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